INVERSIONAL DEPENDENCE OF HYPERFINE QUADRUPOLE COUPLING IN NH-14(3)

被引：19

作者：

SPIRKO, V

机构：

[1] J. Heyrovský Institute of Physical Chemistry and Electrochemistry, Czechoslovak Academy of Sciences, 160 00 Prague 6

来源：

MOLECULAR PHYSICS | 1979年 / 38卷 / 06期

关键词：

D O I：

10.1080/00268977900102841

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A simple theoretical model explaining the inversional dependence of hyperfine quadrupole coupling in 14NH3 is presented. The model, when related to available experimental hyperfine splittings, can be used to predict the effective hyperfine quadrupole coupling constants for all (low-lying) ro-inversional levels. The actual predictions reveal that the inversional dependence of the coupling constants is not only rather strong but also non-monotonic. © 1979 Taylor & Francis Ltd.

引用

页码：1761 / 1766

页数：6

共 8 条

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