DETERMINATION OF THE ELECTRIC-FIELD GRADIENT IN RBCAF3 NEAR THE PHASE-TRANSITION

被引:4
作者
HEPP, MA [1 ]
MAN, PP [1 ]
TROKINER, A [1 ]
ZANNI, H [1 ]
FRAISSARD, J [1 ]
机构
[1] ESPCI,PHYS THERM LAB,PMMH LAB,CNRS,URA 857,F-75005 PARIS,FRANCE
关键词
D O I
10.1016/0038-1098(92)90449-J
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The fluoroperovskite, RbCaF3 undergoes a phase transition at 195.5K from a cubic to a tetragonal phase. The order parameter for this transition is directly related to the electric field gradient which arises in the tetragonal phase. In this work, we have used three NMR methods to measure the electric field gradient at the Rb-87 site in a single crystal of RbCaF3, very near this transition. These experiments are based on recent theoretical developments which allow the measurement of quadrupole parameters even for nuclei in a weak electric field gradient.
引用
收藏
页码:869 / 873
页数:5
相关论文
共 11 条
[1]  
ABRAGAM A, 1961, PRINCIPLES NUCLEAR M
[2]  
BORSA F, 1991, TOP CURR PHYS, V45, P83
[3]  
BULOU A, 1979, J PHYS LETT-PARIS, V40, pL277, DOI 10.1051/jphyslet:019790040013027700
[4]   MULTIPOLE THEORY OF SOFT PULSES IN NMR OF QUADRUPOLAR SOLIDS [J].
CAMPOLIETI, G ;
SANCTUARY, BC ;
COLE, HBR .
JOURNAL OF MAGNETIC RESONANCE, 1990, 88 (03) :457-472
[5]   DETERMINATION OF THE QUADRUPOLAR COUPLING-CONSTANT IN POWDERED SAMPLES WITH A 2 IN-PHASE RF PULSE SEQUENCE IN SOLID-STATE NMR [J].
MAN, PP .
CHEMICAL PHYSICS LETTERS, 1990, 168 (02) :227-232
[8]  
RIDOU C, 1977, J PHYS LETT, V36, pL359
[9]   STUDY OF A STRUCTURAL PHASE-TRANSITION BY 2 DIMENSIONAL FOURIER-TRANSFORM NMR METHOD [J].
TROKINER, A ;
MAN, PP ;
THEVENEAU, H ;
PAPON, P .
SOLID STATE COMMUNICATIONS, 1985, 55 (11) :929-931
[10]   THE STRUCTURAL PHASE-TRANSITION IN RBCAF3 - AN RB-87 NUCLEAR MAGNETIC-RESONANCE INVESTIGATION AT VARIOUS PRESSURES [J].
TROKINER, A ;
ZANNITHEVENEAU, H .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1988, 21 (28) :4913-4930