STUDIES ON TRANSITION-METAL OXO AND NITRIDO COMPLEXES .13. PERRUTHENATE AND RUTHENATE ANIONS AS CATALYTIC ORGANIC OXIDANTS

被引：56

作者：

BAILEY, AJ ^{[1
]}

GRIFFITH, WP ^{[1
]}

MOSTAFA, SI ^{[1
]}

SHERWOOD, PA ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,INORGAN CHEM LABS,LONDON SW7 2AY,ENGLAND

来源：

INORGANIC CHEMISTRY | 1993年 / 32卷 / 03期

关键词：

D O I：

10.1021/ic00055a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The [RuO4]-ion can be generated in aqueous base at pH 11 from aquated ruthenium trichloride with excess bromate, and this reagent will catalytically oxidize primary alcohols, activated alkyl halides, aldehydes, 1,2-diols, and nitroalkanes to carboxylic acids, while secondary alcohols and secondary halides are oxidized to ketones, bromate being the cooxidant. These oxidations are compared with those effected catalytically by trans-[Ru(OH)2O3]2- in aqueous base at pH 14 with persulfate as cooxidant. A new preparation for organic-soluble salts of [RuO4]- avoiding the use of RuO4 is described.

引用

页码：268 / 271

页数：4

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