FACILE PREPARATION OF THE C-60 MONOANION IN APROTIC-SOLVENTS

被引：27

作者：

BOULAS, P

SUBRAMANIAN, R

KUTNER, W

JONES, MT

KADISH, KM

机构：

[1] Department of Chemistry, University of Houston, Texas 77204-5641, Houston

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1993年 / 140卷 / 08期

关键词：

D O I：

10.1149/1.2220841

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A facile method of C60- monoanion preparation in various aprotic solvents is presented and interpreted in terms of the Nernst electrochemical equilibria. The method consists of reduction of C60 with mercury in the presence of tetraalkylammonium halide. The C60- radical product, containing traces of C-60(2-), is detected and identified by electron spin resonance spectroscopy. The selectivity of the method is tuned by a proper selection of solvent, tetraalkylammonium halide, and its concentration.

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页码：L130 / L132

页数：3

相关论文

共 17 条

[1] THE UNUSUAL ELECTRON-SPIN-RESONANCE OF FULLERENE C60.- [J].

ALLEMAND, PM ;

SRDANOV, G ;

KOCH, A ;

KHEMANI, K ;

WUDL, F ;

RUBIN, Y ;

DIEDERICH, F ;

ALVAREZ, MM ;

ANZ, SJ ;

WHETTEN, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (07) :2780-2781

[2] ELECTROREDUCTION OF BUCKMINSTERFULLERENE, C-60, IN APROTIC-SOLVENTS - ELECTRON-SPIN-RESONANCE CHARACTERIZATION OF SINGLY, DOUBLY, AND TRIPLY REDUCED C-60 IN FROZEN-SOLUTIONS [J].

DUBOIS, D ;

JONES, MT ;

KADISH, KM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (16) :6446-6451

[3] ELECTROREDUCTION OF BUCKMINSTERFULLERENE, C-60, IN APROTIC-SOLVENTS - SOLVENT, SUPPORTING ELECTROLYTE, AND TEMPERATURE EFFECTS [J].

DUBOIS, D ;

MONINOT, G ;

KUTNER, W ;

JONES, MT ;

KADISH, KM .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (17) :7137-7145

[4]

GLOD BK, 1985, CHEM ANAL-WARSAW, V30, P665

[5] PRODUCTION, SPECTROSCOPY, AND ELECTRONIC-STRUCTURE OF SOLUBLE FULLERENE IONS [J].

GREANEY, MA ;

GORUN, SM .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (19) :7142-7144

[6] SUPERCONDUCTIVITY AT 18-K IN POTASSIUM-DOPED C-60 [J].

HEBARD, AF ;

ROSSEINSKY, MJ ;

HADDON, RC ;

MURPHY, DW ;

GLARUM, SH ;

PALSTRA, TTM ;

RAMIREZ, AP ;

KORTAN, AR .

NATURE, 1991, 350 (6319) :600-601

[7] ALKALI-FULLERIDE SUPERCONDUCTORS - SYNTHESIS, COMPOSITION, AND DIAMAGNETIC SHIELDING [J].

HOLCZER, K ;

KLEIN, O ;

HUANG, SM ;

KANER, RB ;

FU, KJ ;

WHETTEN, RL ;

DIEDERICH, F .

SCIENCE, 1991, 252 (5009) :1154-1157

[8] EPR-SPECTRUM OF C60- TRAPPED IN MOLECULAR-SIEVE 13X [J].

KEIZER, PN ;

MORTON, JR ;

PRESTON, KF ;

SUGDEN, AK .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (19) :7117-7118

[9] SIMULTANEOUS CYCLIC VOLTAMMETRY AND ELECTROCHEMICAL QUARTZ CRYSTAL MICROBALANCE STUDIES OF BUCKMINSTERFULLERENE (C-60) FILM ELECTRODEPOSITION AND TETRA-NORMAL-BUTYLAMMONIUM ELECTRODOPING IN ACETONITRILE [J].

KOH, W ;

DUBOIS, D ;

KUTNER, W ;

JONES, MT ;

KADISH, KM .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (11) :4163-4165

[10] ELECTROCHEMICAL DETECTION OF C60(6-) AT LOW-TEMPERATURE [J].

OHSAWA, Y ;

SAJI, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (10) :781-782