1,2,3-BENZOTRIAZINES .4. CHEMICAL REACTIVITY OF BENZIMIDAZO[1,2-C][1,2,3]BENZOTRIAZINE

被引:7
作者
SPECTOR, RH
JOULLIE, MM
机构
[1] Chemistry Department, University of Pennsylvania, Philadelphia, Pennsylvania
关键词
D O I
10.1002/jhet.5570060502
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reactions of benzimidazo[1,2‐c][1,2,3]benzotriazine (1) with fluoroboric acid, potassium iodide and phenyl isothiocyanate are described. The structure of the phenyl isothiocyanate product is elucidated by chemical and spectroscopic techniques. The reaction of 1 with alcoholic potassium hydroxide is shown to proceed by a free radical mechanism. The structure of the compound formed from 1 and sodium diethyl malonate is investigated by spectroscopic methods. The reduction and photochemical reactivity of 1 are also discussed. Copyright © 1969 Journal of Heterocyclic Chemistry
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