THIENO[3,4-C]ISOTHIAZOLE - SYNTHESIS AND PROPERTIES OF A NEW NON-CLASSICAL CONDENSED THIOPHENE

被引：11

作者：

GOTTHARDT, H ^{[1
]}

REITER, F ^{[1
]}

GLEITER, R ^{[1
]}

BARTETZKO, R ^{[1
]}

机构：

[1] TH DARMSTADT,INST ORGAN CHEM,D-6100 DARMSTADT,FED REP GER

来源：

CHEMISCHE BERICHTE-RECUEIL | 1979年 / 112卷 / 01期

关键词：

D O I：

10.1002/cber.19791120123

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Das Triphenylthieno[3,4‐c]isothiazol 3 ist ein neuer 10 π‐Heteroaromat, der zwei verschiedene maskierte 1,3‐dipolare Systeme beinhaltet. Seine Synthese aus 4‐Phenyl‐1,3,2‐oxathiazolylium‐5‐olat (1) und Dibenzoylacetylen über die direkte Vorstufe 2 sowie sein Photoelektronen‐ und Elektronenspektrum werden beschrieben. Die an 3 beobachteten Elektronenübergänge werden mit den Ergebnissen einer PPP‐CI‐Rechnung verglichen. Copyright © 1979 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：260 / 265

页数：6

共 27 条

[1] MOLECULAR-PROPERTIES AND MODELS .6. MOLECULAR STATES AND MOLECULAR-ORBITALS [J].

BOCK, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (09) :613-637

[2] SYNTHESIS OF 2 NONCLASSICAL THIENOTHIADIAZOLES [J].

BOWER, JD ;

SCHLESSINGER, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (24) :6891-+

[3] REACTIVE TETRAVALENT SULFUR INTERMEDIATES . A NONCLASSICAL THIOPHTHENE [J].

CAVA, MP ;

POLLACK, NM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (14) :3639-&

[4] NONCLASSICAL CONDENSED THIOPHENES [J].

CAVA, MP ;

LAKSHMIKANTHAM, MV .

ACCOUNTS OF CHEMICAL RESEARCH, 1975, 8 (04) :139-144

[5] NONCLASSICAL CONDENSED THIOPHENES .2. TETRAPHENYLTHIENO[3,4-C]THIOPHENE [J].

CAVA, MP ;

BEHFOROU.M ;

HUSBANDS, GE ;

SRINIVAS.M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (08) :2561-2564

[6] TETRAPHENYLTHIENO[3,4-C]THIOPHENE . A STABLE NONCLASSICAL THIOPHENE [J].

CAVA, MP ;

HUSBANDS, GE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (14) :3952-&

[7] NONCLASSICAL CONDENSED THIOPHENES .4. DERIVATIVES OF THIENO[3,4-C]FURAN-SIV AND THIENO[3,4-C]PYRROLE-SIV [J].

CAVA, MP ;

SPRECKER, MA ;

HALL, WR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (06) :1817-1821

[8] PPP-CALCULATIONS AND COMPARISON OF ELECTRONIC SPECTRA OF ISO-PI-ELECTRONIC OXYGEN NITROGEN SULFUR AND SELENIUM HETEROCYCLES [J].

FABIAN, J ;

MEHLHORN, A ;

ZAHRADNI.R .

THEORETICA CHIMICA ACTA, 1968, 12 (03) :247-&

[9]

GLEITER R, UNPUBLISHED

[10] CRYSTAL-STRUCTURE OF TETRAPHENYLTHIENO[3,4-C]THIOPHENE, A NONCLASSICAL THIOPHENE [J].

GLICK, MD ;

COOK, RE .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1972, B 28 (MAY15) :1336-&

← 1 2 3 →