SYNTHESIS OF STABLE CHROMIUM(V) COMPLEXES OF TERTIARY HYDROXY-ACIDS

被引：225

作者：

KRUMPOLC, M ^{[1
]}

ROCEK, J ^{[1
]}

机构：

[1] UNIV ILLINOIS,DEPT CHEM,CHICAGO,IL 60680

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 12期

关键词：

D O I：

10.1021/ja00506a013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stable, water-soluble chromium(V) complexes of the general formula Na[0Cr(02C0CR1R2)2] were prepared in 60-90% yields by the reaction of anhydrous sodium dichromate in acetone with tertiary α-hydroxy acids (2-hydroxy-2-methylpropionic, 2-hydroxy-2-methylbutyric, 2-ethyl-2-hydroxybutyric, 2-butyl-2-hydroxyhexanoic, 1 -hydroxycyclopentanecarboxylic, 1-hydroxycyclohexanecarboxylic, and 2-hydroxy-2-phenylpropionic acids). © 1979, American Chemical Society. All rights reserved.

引用

页码：3206 / 3209

页数：4

共 8 条

[1]

KOLTHOFF IM, 1965, VOLUMETRIC ANAL, V3, P332

[2]

KRUMPOLC M, 1977, J AM CHEM SOC, V99, P137, DOI 10.1021/ja00443a026

[3] STABLE CHROMIUM(V) COMPOUND - SYNTHESIS, PROPERTIES, AND CRYSTAL-STRUCTURE OF POTASSIUM BIS(2-HYDROXY-2-METHYLBUTYRATO)-OXOCHROMATE(V) MONOHYDRATE [J].