SCALING THEORY OF SUPERMOLECULAR STRUCTURES IN BLOCK COPOLYMER SOLVENT SYSTEMS .2. SUPERCRYSTALLINE STRUCTURES

被引：49

作者：

BIRSHTEIN, TM ^{[1
]}

ZHULINA, EB ^{[1
]}

机构：

[1] ACAD SCI USSR,INST MACROMOLEC COMPOUNDS,LENINGRAD,USSR

来源：

POLYMER | 1990年 / 31卷 / 07期

关键词：

composition-concentration diagram of state; concentrated solution of block copolymer; supermolecular structure;

D O I：

10.1016/0032-3861(90)90223-L

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The supermolecular structures formed in a block copolymer-solvent system were considered by using the scaling method. The equilibrium characteristics of the superstructures of different morphologies formed by two-block copolymers with non-crystallizable blocks were determined as a function of the molecular weight and composition of copolymer and the strength and concentration of the solvent in the system. The composition-concentration diagram of the system was obtained. The lamellar superstructure formed by a block copolymer with one crystallizable block was analysed. The results of the theory were compared with the experimental data. © 1990.

引用

页码：1312 / 1320

页数：9

共 30 条

[1] EFFECT OF ARM NUMBER AND ARM MOLECULAR-WEIGHT ON THE SOLID-STATE MORPHOLOGY OF POLY(STYRENE-ISOPRENE) STAR BLOCK COPOLYMERS
ALWARD, DB
KINNING, DJ
THOMAS, EL
FETTERS, LJ
[J]. MACROMOLECULES, 1986, 19 (01) : 215 - 224
[2] [Anonymous], 1979, SCALING CONCEPTS POL
[3] SCALING THEORY OF SUPERMOLECULAR STRUCTURES IN BLOCK COPOLYMER SOLVENT SYSTEMS .1. MODEL OF MICELLAR STRUCTURES
BIRSHTEIN, TM
ZHULINA, EB
[J]. POLYMER, 1989, 30 (01) : 170 - 177
[4] BIRSHTEIN TM, 1985, VYSOKOMOL SOEDIN A+, V27, P1613
[5] BIRSHTEIN TM, 1988, VYSOKOMOL SOEDIN B, V30, P387
[6] BIRSHTEIN TM, 1984, POLYMER, V25, P1435
[7] BIRSHTEIN TM, 1986, POLYMER, V27, P1079
[8] STAR SHAPED POLYMERS - A MODEL FOR THE CONFORMATION AND ITS CONCENTRATION-DEPENDENCE
DAOUD, M
COTTON, JP
[J]. JOURNAL DE PHYSIQUE, 1982, 43 (03): : 531 - 538
[9] CALCULATION OF LAMELLAR THICKNESS IN A DIBLOCK CO-POLYMER, ONE OF WHOSE COMPONENTS IS CRYSTALLINE
DIMARZIO, EA
GUTTMAN, CM
HOFFMAN, JD
[J]. MACROMOLECULES, 1980, 13 (05) : 1194 - 1198
[10] DOUY A, 1973, MAKROMOL CHEM, V165, P297

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