VIBRATIONAL-RELAXATION OF NO BY ATOMIC OXYGEN

被引：80

作者：

FERNANDO, RP

SMITH, IWM

机构：

[1] Department of Physical Chemistry, University Chemical Laboratories, Cambridge

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 66卷 / 02期

关键词：

D O I：

10.1016/0009-2614(79)85002-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A laser-induced fluorescence method has been used to study the vibrational relaxation of NO by atomic oxygen, i.e. NO(v=1) + O - NO(v=0) + O(2). The NO was excited indirectly by vibrational-vibrational energy transfer from HCI(v=1), these molecules having been prepared using the output from a pulsed HCl chemical laser. The experiments yield: k2=(6.5 ± 0.7) × 10-11 cm3 molecule-1 s-1 at (296 ± 3) K. © 1979.

引用

页码：218 / 222

页数：5

共 22 条

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