INSERTION OF CS2 INTO CU-S BONDS .2. PREPARATION AND CRYSTAL-STRUCTURE OF INSERTION PRODUCT WITH CS2 [CU6(S2CSC6H2PRI3-2,4,6)4(SC6H2PRI3-2,4,6)2].2CHCL3.4CH3OH

被引：8

作者：

TANG, KL

WU, DD

JIN, XL

TANG, YQ

机构：

[1] Institute of Physical Chemistry, Peking University, Beijing

来源：

HETEROATOM CHEMISTRY | 1992年 / 3卷 / 5-6期

关键词：

D O I：

10.1002/hc.520030532

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complex [Cu(SC6H2Pri3-2,4,6)]8 (1) reacts with a small amount of CS2 to give red CrYStals [Cu6(S2CSC6H2Pri3-2,4,6)4(SC6H2Pri3-2,4,6)2] . 2CHCl3.4CH3OH (2), and CS2 is inserted into two-thirds of the Cu-S bonds of complex (1). The unusual structure of complex (2) consists of six copper atoms linked through arene-thiolate (RS-) and aryl trithiocarbonate (RSCS2-) ligands, exhibiting a number of interesting features. Crystal data: triclinic, space group P1BAR a = 14.298(4), b = 14.282(5), c = 17.745(7) angstrom, alpha = 109.92(3), beta = 111.88(3), gamma = 90.42(2)-degrees, Z = 1, R = 7.83%, for 4118 observed reflections.

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页码：655 / 659

页数：5

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