SYNTHESIS OF CARBOHYDRATE CONTAINING CROWN ETHERS AND THEIR APPLICATION AS CATALYSTS IN ASYMMETRIC MICHAEL ADDITIONS

被引：41

作者：

VANMAARSCHALKERWAART, DAH ^{[1
]}

WILLARD, NP ^{[1
]}

PANDIT, UK ^{[1
]}

机构：

[1] UNIV AMSTERDAM,ORGAN CHEM LAB,NIEUWE ACHTERGRACHT 129,1018 WS AMSTERDAM,NETHERLANDS

来源：

TETRAHEDRON | 1992年 / 48卷 / 40期

关键词：

CHIRAL CROWN ETHERS; CARBOHYDRATES; ASYMMETRIC CATALYSIS; ASYMMETRIC MICHAEL ADDITIONS;

D O I：

10.1016/S0040-4020(01)89454-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Synthesis of carbohydrate containing crown ethers tuned with steric and micro-environmental features and their application as catalysts in the Michael addition of methyl phenylacetate to methyl acrylate to give a chiral product is reported. The mechanistic rationale of the asymmetric induction is discussed.

引用

页码：8825 / 8840

页数：16

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