CHEMOSELECTIVE AND REGIOSELECTIVE ISOMERIZATION OF EPOXIDES TO CARBONYL-COMPOUNDS VIA PALLADIUM CATALYSIS

被引：63

作者：

KULASEGARAM, S ^{[1
]}

KULAWIEC, RJ ^{[1
]}

机构：

[1] GEORGETOWN UNIV,DEPT CHEM,WASHINGTON,DC 20057

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 24期

关键词：

D O I：

10.1021/jo00103a005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium(O)-tertiary phosphine complexes catalyze the chemo- and regioselective isomerization of epoxides to carbonyl compounds in good to excellent yields; alkyl-substituted epoxides afford methyl ketones, and aryl-substituted epoxides form aldehydes or ketones via cleavage of the benzylic C-O bond.

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页码：7195 / 7196

页数：2

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