MECHANISM OF CD2+ DISCHARGE FROM NON-COMPLEXING AQUEOUS-ELECTROLYTE IN PRESENCE AND ABSENCE OF NEUTRAL ADSORBABLE COMPOUNDS

被引:29
作者
KISOVA, L
GOLEDZINOWSKI, M
LIPKOWSKI, J
机构
[1] Laboratory of Electroanalytical Chemistry, University of Warsaw, 02093 Warsaw
关键词
D O I
10.1016/S0022-0728(79)80217-X
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The mechanism of Cd2+ discharge and cadmium amalgam dissolution in the absence and presence of organic neutral surfactants is compared. The generality of the stepwise mechanism of this reaction occurring on Hg electrode both covered and non-covered by the surfactants is shown. The reliability of the existence of Cd+ as an intermediate in the electrode reaction is discussed. © 1979 Elsevier Sequoia S.A.
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页码:29 / 42
页数:14
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