COMPETITIVE KINETICS OF 1,2-CARBON AND HYDRIDE SHIFTS IN CYCLOBUTYLCHLOROCARBENE

被引：15

作者：

MOSS, RA

HO, GJ

机构：

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 09期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)88771-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cyclobutylchlorocarbene undergoes competitive 1,2-carbon and 1,2-hydride intramolecular rearrangements with (approximate) absolute rate constants of 4.6 x 107 and 2.1 x 107 s-1, respectively, at 21°C. © 1990.

引用

页码：1225 / 1228

页数：4

共 18 条

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