REGIOSELECTIVE CONVERSION OF O-PROTECTED GLYCIDOLS TO FLUOROHYDRINS CATALYZED BY TETRABUTYLAMMONIUM DIHYDROGENTRIFLUORIDE UNDER SOLID-LIQUID PTC CONDITIONS

被引：31

作者：

LANDINI, D ^{[1
]}

ALBANESE, D ^{[1
]}

PENSO, M ^{[1
]}

机构：

[1] UNIV MILAN,DIPARTIMENTO CHIM ORGAN & IND,I-20133 MILAN,ITALY

来源：

TETRAHEDRON | 1992年 / 48卷 / 20期

关键词：

D O I：

10.1016/S0040-4020(01)92194-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A number of O-protected glycidols are regioselectively converted into the corresponding fluorohydrins FCH2CH(OH)CH2OX by reaction with catalytic amounts of Bu4N+H2F3- and a molar excess of KHF2. Most of the protective groups (X) examined are stable under the above conditions, moreover stereogenic carbons are not affected.

引用

页码：4163 / 4170

页数：8

共 23 条

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