RAMAN, PRERESONANCE RAMAN AND ELECTRONIC-SPECTRA OF THE ANION [VO2Q2]-(Q = 8-HYDROXYQUINOLINATE)

被引：20

作者：

JUBERT, AH ^{[1
]}

BARO, ACG ^{[1
]}

DIEZ, RP ^{[1
]}

BARAN, EJ ^{[1
]}

机构：

[1] NATL UNIV LA PLATA,FAC CIENCIAS EXACTAS,CC 962,RA-1900 LA PLATA,ARGENTINA

来源：

JOURNAL OF RAMAN SPECTROSCOPY | 1992年 / 23卷 / 05期

关键词：

D O I：

10.1002/jrs.1250230506

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The Raman spectrum of Na[VO2Q2] was recorded and asssigned by comparison with related species. The excitation profiles of the vibrational modes that show pre-resonance on excitation using laser radiation within the electronic bands are reported and three different types of profiles could be found. The electronic spectrum of the anion was also recorded and interpreted with the aid of a semi-empirical MO calculation. This calculation, together with the results of the pre-resonance experiments, also reinforced some of the vibrational assignments.

引用

页码：273 / 279

页数：7

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