MACROCYCLIC LIQUID-CRYSTALS FROM FUNCTIONALIZED THIOETHER CROWNS - THE SINGLE-CRYSTAL X-RAY STRUCTURES OF CIS-R(2)[14]ANES(4) AND TRANS-R(2)[14]ANES(4) (R=O(2)CC(6)H(4)OME-4)

被引:16
作者
BLAKE, AJ
BRUCE, DW
FALLIS, IA
PARSONS, S
SCHRODER, M
机构
[1] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND
[2] UNIV SHEFFIELD,CTR MOLEC MAT,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND
[3] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND
关键词
D O I
10.1039/c39940002471
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The syntheses of cis and trans oligobenzoate ester derivatives R(2)[14]aneS(4) are described; the structures of the cis and trans derivatives for R = O(2)CC(6)H(4)OMe-4 are dominated by intermolecular packing between benzoate ester units, while the cis and trans derivatives for R = O2CC6H4(O2CC6H4OC8H17-4)-4 both show nematic mesophases.
引用
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页码:2471 / 2473
页数:3
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