DIRECT MEASUREMENT OF ROTATIONAL CORRELATION TIMES OF LUMINESCENT RUTHENIUM(II) MOLECULAR PROBES BY DIFFERENTIAL POLARIZED PHASE FLUOROMETRY

被引：18

作者：

DEGRAFF, BA

DEMAS, JN

机构：

[1] UNIV VIRGINIA, DEPT CHEM, CHARLOTTESVILLE, VA 22901 USA

[2] JAMES MADISON UNIV, DEPT CHEM, HARRISONBURG, VA 22807 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 48期

关键词：

D O I：

10.1021/j100099a006

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Direct measurements of rotational correlation times of luminescent ruthenium(II) probes (RuL(3)(2+), RuL(2)L(2+) and RuL(2)(CN)(2), L and L' = alpha-diimine) by differential polarization phase fluorimetry have been made. Correlation times and limiting anisotropies are related to structural parameters of the complexes. Implications for the use and design of metal complexes as dynamic probes of motions of macromolecular systems such as organic and biopolymers are given.

引用

页码：12478 / 12480

页数：3

共 17 条

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