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ALICYCLIC COMPOUNDS .3. ACTION OF BASE ON BICYCLIC KETOTOSYLATES - A NOVEL SOLVOLYTIC REARRANGEMENT TO BICYCLO-3-2-0-HEPTENONE DERIVATIVE

被引：12
作者：
MUKHARJI, PC
GANGULY, AN
机构：
[1] Department of Chemistry, Presidency College, Calcutta
来源：
TETRAHEDRON | 1969年 / 25卷 / 21期
关键词：
D O I：
10.1016/0040-4020(69)80049-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The action of KOBut on 10-hydromethyl-Δ3,4-2-octalone tosylate (X) furnished the ketone (XVI) containing a bicyclo[3.2.0]heptanone moiety through solvolytic rearrangement of the homoallylic system. The isomeric 10-hydromethyl-Δ1,9-2-octalone tosylate (XX) however, gave the tricyclic ketone (XXI) without rearrangement.2 2 Presented at the joint annual convention of the Chemical Research Committee of the Council of Scientific and Industrial Research, India and the Society of Biological Chemists (India) at the University of Delhi, December 1966. © 1969.
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页码：5281 / &
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