A ROUTE TO SPIROKETALS USING RADICAL TRANSLOCATION

被引：19

作者：

BROWN, CDS

SIMPKINS, NS

CLINCH, K

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,UNIV PK,NOTTINGHAM NG7 2RD,ENGLAND

[2] ICI AGROCHEM,JEALOTTS HILL RES STN,BRACKNELL RG12 6EY,BERKS,ENGLAND

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 01期

关键词：

D O I：

10.1016/S0040-4039(00)60075-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of beta-iodoenones of general structure 4 with Bu3SnH leads to formation of spiroketal products via 1,5-translocation of the initially formed radical.

引用

页码：131 / 132

页数：2

共 8 条

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[3] (E)-3-(TRIMETHYLSILYL)-2-PROPEN-1-OL - AN IMPROVED PREPARATION
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[6] A NEW STEREOSELECTIVE SYNTHESIS OF (Z)-VINYLSILANE ALLYLIC ALCOHOLS
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MAGRIOTIS, PA
[J]. TETRAHEDRON LETTERS, 1990, 31 (43) : 6137 - 6140
[7] SYNTHESIS OF N-PROTECTED SPIROAMINES RELATED TO NATURAL-PRODUCTS USING RADICAL CYCLIZATIONS
MIDDLETON, DS
SIMPKINS, NS
[J]. TETRAHEDRON LETTERS, 1989, 30 (29) : 3865 - 3868
[8] SYNTHESIS OF SPIROETHERS USING RADICAL CYCLIZATIONS
MIDDLETON, DS
SIMPKINS, NS
BEGLEY, MJ
TERRETT, NK
[J]. TETRAHEDRON, 1990, 46 (02) : 545 - 564

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