PREPARATION OF POLY(PARA-PHENYLENE) BY ELECTROOXIDATIVE POLYMERIZATION IN ACIDIC MEDIA

被引：38

作者：

YAMAMOTO, K ^{[1
]}

ASADA, T ^{[1
]}

NISHIDE, H ^{[1
]}

TSUCHIDA, E ^{[1
]}

机构：

[1] WASEDA UNIV, DEPT POLYMER CHEM, TOKYO 160, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1988年 / 61卷 / 05期

关键词：

ACIDS - ALUMINUM COMPOUNDS - CATALYSTS - Materials - ELECTROLYTES - Materials;

D O I：

10.1246/bcsj.61.1731

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electro-oxidative polymerization of benzene in the presence of strong acids yields poly(p-phenylene) efficiently. A strong protonic acid such as trifluoromethanesulfonic acid or Lewis acid such as an aluminum trichloride forms a complex with benzene and reduces the oxidation potential of benzene to 1. 7 V, which brings about the high current efficiency. The acids act both as an electrolyte and as a catalyst in this polymerization of benzene.

引用

页码：1731 / 1734

页数：4

共 23 条

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