ELECTROCHEMICAL INCORPORATION OF CARBON-DIOXIDE INTO ALKENES BY NICKEL-COMPLEXES

被引：74

作者：

DERIEN, S

CLINET, JC

DUNACH, E

PERICHON, J

机构：

[1] CNRS,ELECTROCHIM CATALYSE & SYNTHESE ORGAN LAB,UMR 28,F-94320 THIAIS,FRANCE

[2] UNIV PARIS 11,INST CHIM MOLEC ORSAY,F-91405 ORSAY,FRANCE

来源：

TETRAHEDRON | 1992年 / 48卷 / 25期

关键词：

D O I：

10.1016/S0040-4020(01)89021-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Electrogenerated Ni(0) complexes from stable Ni(II) compounds are the catalysts for the electrochemical incorporation of carbon dioxide into carbon-carbon double bonds. Different kind of olefin derivatives have been carboxylated to afford mono- or dicarboxylic acid derivatives depending on the alkene structure. The electrolyses are carried out in one compartment cells fitted with a magnesium anode under mild conditions.

引用

页码：5235 / 5248

页数：14

共 40 条

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