GAS-PHASE ION-MOLECULE REACTIONS OF THE CH30+ CATION

被引：22

作者：

ZAPPEY, HW ^{[1
]}

INGEMANN, S ^{[1
]}

NIBBERING, NMM ^{[1
]}

机构：

[1] UNIV AMSTERDAM,INST MASS SPECTROMETRY,NIEUWE ACHTERGRACHT 129,1018 WS AMSTERDAM,NETHERLANDS

来源：

JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY | 1992年 / 3卷 / 05期

关键词：

D O I：

10.1016/1044-0305(92)85028-I

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

The methoxy cation, CH3O+, formed by collision-induced charge reversal of methoxy anions with a kinetic energy of 8 keV, has been differentiated from the isomeric CH2OH+ ion by performing low kinetic energy ion-molecule reactions in the radiofrequency-only quadrupole of a reverse-geometry double-focusing quadrupole hybrid mass spectrometer. The methoxy cation reacts with CH3SH, CH3 - CH = CH2, (CH3)20, and CH3CH2Cl by electron transfer, whereas the 4CH2OH+ ion reacts by proton transfer with these substrates

引用

页码：515 / 517

页数：3

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