TINB, ZRNB, ZRV, AND HFV MOLECULES - ESR, GROUND-STATES, AND ISOVALENCY

被引：9

作者：

VANZEE, RJ ^{[1
]}

LI, S ^{[1
]}

WELTNER, W ^{[1
]}

机构：

[1] UNIV FLORIDA, CTR CHEM PHYS, GAINESVILLE, FL 32611 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1995年 / 103卷 / 07期

关键词：

D O I：

10.1063/1.470511

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electron-spin-resonance (ESR) spectroscopy of these molecules in argon matrices at 2 K reveals that each has a (4) Sigma ground electronic state, the same as TiV, also containing 9 valence (s+d) electrons. TiTa and ZrTa were not observed. An analogy can be drawn with the 15-valence-electron Brewer-Engel molecules VNi, VPd, VPt, NbNi, which also have (4) Sigma ground states and a ...sigma(1)d delta(2) configuration, where sigma is an sd sigma hybrid. (C) 1995 American Institute of Physics.

引用

页码：2762 / 2765

页数：4

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