REACTION OF DELTA(3)-CARBENE WITH DICHLOROCARBENE AND CHLOROCARBENE . NUCLEAR MAGNETIC RESONANCE OF TRANS-1,4,4-TRIMETHYL-TRICYCLO[5.1.0.0.(3,5)]OCTANE

被引：17

作者：

FRISCHLEDER, H

GRAEFE, J

VANPHIET, H

MUHLSTAD.M

机构：

来源：

TETRAHEDRON | 1969年 / 25卷 / 10期

关键词：

D O I：

10.1016/S0040-4020(01)82759-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dichloro- and chlorocarbenes exclusively attack Δ3-carene from the side opposite to the gem-dimethylcyclopropyl group. The trans-1,4,4-trimethyl-tricyclo[5.1.0.03,5]octanes V, VI and VII so obtained, each exist in two conformations with nearly flat 6-membered rings. © 1969.

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页码：2081 / +

页数：1

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