LOW PRESSURE OLIGOMERIZATION OF MONO-OLEFINS WITH SOLUBLE NICKEL/ALUMINUM BIMETAL CATALYSTS .1. DEVELOPMENT OF NEW CATALYST SYSTEMS BASED ON PI-CYCLOBUTADIENE-NICKEL(2) COMPOUNDS

被引:35
作者
ONSAGER, OT
WANG, H
BLINDHEI.U
机构
[1] Zentralinstitut für Industrielle Forschung, Oslo, Blindern
关键词
D O I
10.1002/hlca.19690520119
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mixtures of π‐tetramethylcyclobutadiene‐nickeldihalides and LEWIS acids such as alkylaluminiumhalides in organic solvents represent new highly active homogeneous catalysts for the dimerization of ethylen, propene and butene under mild conditions. As a cocatalyst LEWIS bases may be used, in particular those containing trivalent phosphorous. Copyright © 1969 Verlag GmbH & Co. KGaA, Weinheim
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页码:187 / &
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