SUBSTITUENT EFFECTS IN POLAROGRAPHY OF AROMATIC DIAZONIUM SALTS

被引：161

作者：

ELOFSON, RM

GADALLAH, FF

机构：

[1] Research Council of Alberta, Edmonton

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 04期

关键词：

D O I：

10.1021/jo01256a016

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Polarographic reduction of a number of substituted benzenediazonium tetrafluoroborates in the aprotic solvent, sulfolane, has been carried out. The most positive wave is a reversible one-electron step. The half-wave potential of this wave correlates well with Hammett σ values and is defined by the equation E1/2 = 0.229σ + 0.314 ± 0.024 V. © 1969, American Chemical Society. All rights reserved.

引用

页码：854 / &

共 16 条

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