CARBOHYDRATES IN TOTAL SYNTHESIS OF (-)-ANTIRHINE

被引：10

作者：

PANCRAZI, A ^{[1
]}

KERVAGORET, J ^{[1
]}

KHUONGHUU, Q ^{[1
]}

机构：

[1] CNRS,INST CHIM SUBST NAT,F-91190 GIF SUR YVETTE,FRANCE

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 35期

关键词：

PICTET-SPENGLER CYCLIZATION; ALKALOIDS; CARBOHYDRATES; TOTAL SYNTHESIS; (-)-ANTIRHINE;

D O I：

10.1016/0040-4039(91)80018-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Amide 5 was obtained by condensation between pyranose 3 and tryptamine 4; in few steps, the indoloquinolizidine 13a was prepared with a perfect stereocontrol of the 2-beta-H configuration; total synthesis of (-)-antirhine 2 was then achieved from 13a.

引用

页码：4483 / 4486

页数：4

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