PLASMA-INDUCED NITROGEN CHEMISORPTION ON A RUTHENIUM BLACK CATALYST - FORMATION OF NH3 BY HYDROGENATION OF THE CHEMISORBED NITROGEN

被引：26

作者：

KUNIMORI, K

OSUMI, M

KAMEOKA, S

ITO, S

机构：

[1] Institute of Materials Science, University of Tsukuba, Ibaraki, 305, Tsukuba

来源：

CATALYSIS LETTERS | 1992年 / 16卷 / 04期

关键词：

PLASMA-INDUCED CHEMISORPTION; NITROGEN CHEMISORPTION; RU BLACK CATALYST; PRODUCTION OF AMMONIA; THE REACTIVITY OF CHEMISORBED NITROGEN;

D O I：

10.1007/BF00764903

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nitrogen was chemisorbed on a ruthenium black catalyst by a plasma discharge of N2. Temperature-programmed desorption of nitrogen showed a broad peak at around 300-degrees-C which showed a dependence on the duration and the wattage of the discharge. The chemisorbed nitrogen species was reacted with hydrogen to form NH3 even at room temperature.

引用

页码：443 / 446

页数：4

共 9 条

[1]

[Anonymous], 1962, VACUUM

[2] ADSORPTION AND DESORPTION OF AMMONIA, HYDROGEN, AND NITROGEN ON RUTHENIUM (0001) [J].