EPOXIDES DERIVED FROM PYRANOSYL DIENES - UNUSUALLY STABLE GLYCOSYL DONORS

被引:12
作者
LINK, JT
DANISHEFSKY, SJ
SCHULTE, G
机构
[1] YALE UNIV,DEPT CHEM,NEW HAVEN,CT 06511
[2] YALE UNIV,CTR CHEM INSTRUMENTAT,NEW HAVEN,CT 06511
基金
美国国家卫生研究院;
关键词
D O I
10.1016/0040-4039(94)88445-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A pyranosyl diene appropriately substituted for use in a total synthesis of staurosporine has been synthesized. The mono-epoxides and bis-epoxides obtained from treatment of this diene with dimethyldioxirane are unusually stable.
引用
收藏
页码:9131 / 9134
页数:4
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