PREPARATION AND REACTIONS OF PERFLUORO-BETA-OXA-DELTA-VALEROLACTONE

被引：9

作者：

THROCKMORTON, JR

机构：

[1] Central Research Laboratories, Minnesota Mining and Manufacturing Company, St. Paul, Minnesota

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 11期

关键词：

D O I：

10.1021/jo01263a049

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The preparation of perfluoro-β-oxa-δ-valerolactone (III) from perfluorooxydiacetyl chloride (I) and fluoride (IV) and metal fluorides is described. Reaction of III with excess water, methanol, and ammonia gives perfluorooxydiacetic acid, dimethylperfluorooxy diacetate, and perfluorooxydiacetamide, respectively. Ultraviolet irradiation of III gives perfiuoro-1,3-dioxolane (V). © 1969, American Chemical Society. All rights reserved.

引用

页码：3438 / +

页数：1

共 7 条

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