9,10-PHENANTHRENOCYANINATOIRON(II) (PHCFE) AND AXIALLY COORDINATED ISOCYANIDE COMPLEXES

被引：25

作者：

HANACK, M

RENZ, G

机构：

[1] Institut Für Organische Chemie, Universität Tübingen, Tübingen, D-7400

来源：

CHEMISCHE BERICHTE | 1990年 / 123卷 / 05期

关键词：

9,10‐Phenanthrenocyaninatoiron(II); Isocyanide complexes; Porphyrin derivatives; Semiconductors; organic;

D O I：

10.1002/cber.19901230525

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

9,10‐Phenanthrenocyaninatoiron(II) (PhcFe) and Axially Coordinated Isocyanide Complexes 9,10‐Phenanthrenocyaninatoiron(II) (PhcFe) is synthesized from 9,10‐dicyanophenanthrene (3) and pentacarbonyliron. PhcFe exhibits similar spectroscopic properties (UV/VIS and Mößbauer spectra) and similar oxidation potentials as 1,2‐Naphthalocyaninatoiron(II) (1,2‐NcFe) and Phthalocyaninatoiron(II) (PcFe). Isocyanides RNC (R = tBu, cHx, Bzl, Me2Ph) react with PhcFe to form the corresponding bisaxially substituted 9,10‐phenanthrenocyaninatoiron(II) compounds 4–7. Reaction of PhcFe with 1,4‐diisocyanobenzene (dib) yields the bridged complex [PhcFe(dib)]n. Copyright © 1990 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：1105 / 1110

页数：6

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