DIRECT TRANSFORMATION OF 6-COORDINATE TO 3-COORDINATE PHOSPHORUS IN PARA-TERT-BUTYLCALIX[4]ARENE - THE 1ST X-RAY CRYSTAL-STRUCTURE OF A HYPERVALENT MAIN GROUP ATOM BOUND TO A CALIXARENE

被引：49

作者：

KHASNIS, DV ^{[1
]}

BURTON, JM ^{[1
]}

LATTMAN, M ^{[1
]}

ZHANG, HM ^{[1
]}

机构：

[1] SO METHODIST UNIV, DEPT CHEM, DALLAS, TX 75275 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 08期

关键词：

D O I：

10.1039/c39910000562

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Removal of dimethylamine from the zwitterionic six-coordinate phosphorus species p-tert-butylcalix[4]areneP(H)NHMe2 1 leads to the three-coordinate derivative p-tert-butylcalix[4]arene(H)P 4; the X-ray structure of Li[p-tert-butylcalix[4]areneP(H)NMe2] 3 gives an insight as to why to pentacoordinate species is observed.

引用

页码：562 / 563

页数：2

共 9 条

[1] ATKINS TJ, 1978, TETRAHEDRON LETT, P5149
[2] THE OXO-MOLYBDENUM(VI) GROUP OVER A CALIXARENE-OXO SURFACE - CALIX[4]ARENE COMPLEXING INORGANIC AND ORGANIC FUNCTIONALITIES
CORAZZA, F
FLORIANI, C
CHIESIVILLA, A
GUASTINI, C
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (08) : 640 - 641
[3] Gutsche C. D., 1989, CALIXARENES
[4] GUTSCHE CD, 1990, ORG SYNTH, V68, P234
[5] HOLMES RR, 1980, PENTACOORDINATED PHO, V1, pCH2
[6] PUTTING BOTTOMS ON BASKETS - THE 1ST MAIN-GROUP-ELEMENT SINGLE-ATOM BRIDGE OF A CALIXARENE
KHASNIS, DV
LATTMAN, M
GUTSCHE, CD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (25) : 9422 - 9423
[7] CRYSTAL AND MOLECULAR-STRUCTURE OF BROMOTETRAKIS(TRIMETHYL PHOSPHITO)NICKEL(II) TETRAFLUOROBORATE, [NI[P(OCH3)3]4BR]BF4
MILBRATH, DS
SPRINGER, JP
CLARDY, JC
VERKADE, JG
[J]. INORGANIC CHEMISTRY, 1975, 14 (11) : 2665 - 2668
[8] RICHMAN JE, 1978, TETRAHEDRON LETT, P4333
[9] TEBBY JC, 1987, PHOSPHORUS 31 NMR SP, pCH1

← 1 →