PREPARATION OF SULFONIUM-ETA-3-ALLYLIDE COMPLEXES OF PALLADIUM(II)

被引：8

作者：

NISHIYAMA, H ^{[1
]}

机构：

[1] NAGOYA UNIV, FAC ENGN, DEPT SYNTHET CHEM, NAGOYA, AICHI 464, JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 165卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)82210-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New palladium(II) complexes containing dimethylsulfonium allylide and tetramethylenesulfonium allylide as η3-allyl-ligands were prepared by treatment of the corresponding allyl-sulfonium salt and palladium bromide with sodium acetate. Thermally unstable sulfonium allylides were readily captured on a palladium metal by this straightforward preparation. Spectroscopic results of these new complexes were also discussed. © 1979.

引用

页码：407 / 413

页数：7

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