INTRAMOLECULAR BASE STABILIZATION OF SI=N AND SI=P COMPOUNDS AND RELATED TRANSITION-METAL SILANEDIYL COMPLEXES

被引：81

作者：

CORRIU, R

LANNEAU, G

PRIOU, C

机构：

[1] Laboratoire des Précurseurs Organométalliques de Matériaux, URA, Université des Sciences et Techniques du Languedoc-Case, Montpellier, F-34095

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 09期

关键词：

D O I：

10.1002/anie.199111301

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The high activity of low-coordinated silicon compounds can be effectively reduced by intramolecular base stabilization: thus the silane imine 1 can be distilled at 175-degrees-C/2 x 10(-2) torr without dimerization, the silaphosphene 2 can be sublimed at 220-degrees-C/10(-2) torr, and the silanediyl complexes 3 and 4 can be recrystallized from acetone. [GRAPHICS]

引用

页码：1130 / 1132

页数：3

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