A NOVEL ORGANOMAGNESIUM COMPOUND CONSISTING OF 2 TRIPLE-DECKER CATIONS [LMG(MU-ME)(3)MGL](+) AND AN OCTAMETHYLTRIMAGNESATE ANION - [(ME(2)MG(MU-ME)(2))MG-2](2-)

被引：19

作者：

VIEBROCK, H ^{[1
]}

BEHRENS, U ^{[1
]}

WEISS, E ^{[1
]}

机构：

[1] UNIV HAMBURG, INST ANORGAN & ANGEW CHEM, D-20146 HAMBURG, GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1994年 / 33卷 / 12期

关键词：

D O I：

10.1002/anie.199412571

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The disproportionation of dimethylmagnesium to give novel organomagnesium ions is possible with the tripod ligand N,N′,N″‐trimethyl‐l,4,7‐triazacyclononane (tacn). The cation in 1 has a triple‐decker structure (shown on the right); the anion is the first trimagnesate, whose structure is intermediate to those of monomeric and polymeric compounds. (Formula Presented.) (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1257 / 1259

页数：3

共 17 条

[1] CARBENE ADDUCTS OF MAGNESIUM AND ZINC [J].

ARDUENGO, AJ ;

DIAS, HVR ;

DAVIDSON, F ;

HARLOW, RL .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 462 (1-2) :13-18

[2] REACTIONS OF GRIGNARD-REAGENTS WITH AN AZACROWN ETHER - SYNTHESES OF RMG(14N4)+RMGX2- AND RMG(14N4)+X- [J].

FABICON, RM ;

PAJERSKI, AD ;

RICHEY, HG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (20) :9333-9334

[3] METAL ALKYL AND ARYL COMPOUNDS .25. CRYSTAL-STRUCTURE OF DIMETHYL-(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)MAGNESIUM [J].

GREISER, T ;

KOPF, J ;

THOENNES, D ;

WEISS, E .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 191 (01) :1-6

[4]

MARKIES PR, 1991, ADV ORGANOMET CHEM, V32, P147

[5] INTERACTIONS OF DIALKYLMAGNESIUM COMPOUNDS WITH 15-CROWN-5 - FORMATION IN SOLUTIONS AND SOLIDS OF RMG(15-CROWN-5)+ AND MAGNESIATE IONS [J].

PAJERSKI, AD ;

PARVEZ, M ;

RICHEY, HG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (08) :2660-2662

[6]

Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, DOI 10.1107/S205322961402421825]

[7]

Sheldrick GM, 1986, SHELXS 86 PROGRAM CR

[8] MAGNESIATE IONS IN SOLUTIONS AND SOLIDS PREPARED FROM DIALKYLMAGNESIUM COMPOUNDS AND CRYPTANDS [J].

SQUILLER, EP ;

WHITTLE, RR ;

RICHEY, HG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (02) :432-435

[9] STRUCTURAL PROPERTIES OF DIMETHYLBIS(QUINUCLIDINE)-MAGNESIUM [J].

TONEY, J ;

STUCKY, GD .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1970, 22 (02) :241-&

[10]

VIEBROCK H, 1994, Z NATURFORSCH B, V49, P89

← 1 2 →