RAPID CHARACTERIZATION OF RHODIUM DIHYDRIDES BY NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY USING INDIRECT 2-DIMENSIONAL METHODS AND PARA-HYDROGEN

被引：38

作者：

DUCKETT, SB ^{[1
]}

BARLOW, GK ^{[1
]}

PARTRIDGE, MG ^{[1
]}

MESSERLE, BA ^{[1
]}

机构：

[1] UNIV SYDNEY,DEPT ORGAN CHEM,SYDNEY,NSW 2006,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 20期

关键词：

D O I：

10.1039/dt9950003427

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

When [RhH2(PMe(3))(3)Cl], incorporating chemically inequivalent hydrides, and [RhH2(PMe(3))(4)]Cl, containing magnetically inequivalent hydrides.,were generated using para-enriched hydrogen, their H-1-Rh-103 and H-1-P-31 two-dimensional NMR spectra were quickly obtained from < 1 mg of complex with and without the aid of pulsed field gradients.

引用

页码：3427 / 3429

页数：3

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