POLYMERIC ORGANOSILICON SYSTEM .8. SYNTHESIS OF POLY[(DISILANYLENE)DIETHYNYLENE] WITH HIGHLY CONDUCTING PROPERTIES

被引：72

作者：

ISHIKAWA, M ^{[1
]}

HASEGAWA, Y ^{[1
]}

KUNAI, A ^{[1
]}

YAMANAKA, T ^{[1
]}

机构：

[1] MITSUI PETROCHEM IND CO LTD,SODEGAURA,CHIBA 299,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 381卷 / 03期

关键词：

D O I：

10.1016/0022-328X(90)80071-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of bis(trimethylsilyl)butadiyne with 2 equiv. of methyllithium, followed by 1,2-dichloro-1,2-dimethyldiphenyl- or 1,2-dichloro-1,2-diethyldimethyldisilane gives poly[(1,2-dimethyldiphenyldisilanylene)diethynylene] (II) or poly[(1,2- diethyldimethyldisilanylene)diethynylene] (III), respectively. Films of II and III become conducting when treated with SbF5 vapor. © 1990.

引用

页码：C57 / C59

页数：3

共 8 条

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