NOVEL SELENIUM CATALYZED SYNTHESIS OF ISOTHIOCYANATES FROM ISOCYANIDES AND ELEMENTAL SULFUR

被引：64

作者：

FUJIWARA, S ^{[1
]}

TSUTOMU, S ^{[1
]}

SONODA, N ^{[1
]}

AOKI, M ^{[1
]}

OKADA, K ^{[1
]}

MIYOSHI, N ^{[1
]}

KAMBE, N ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 29期

关键词：

D O I：

10.1016/0040-4039(91)80817-P

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A variety of aliphatic and aromatic isothiocyanates were synthesized in good to excellent yields from corresponding isocyanides and elemental sulfur under mild conditions by use of catalytic amounts of elemental selenium.

引用

页码：3503 / 3506

页数：4

共 17 条

[1]

BLOCK E, 1990, HETEROATOM CHEM

[2]

BLOTNY G, 1982, LIEBIGS ANN CHEM, P1927

[3] SULFURIZATION OF ISOCYANIDES [J].

BOYER, JH ;

RAMAKRIS.VT .

JOURNAL OF ORGANIC CHEMISTRY, 1972, 37 (09) :1360-+

[4] NEW SYNTHESIS OF ISOCYANATES [J].

GITTOS, MW ;

DAVIES, RV ;

IDDON, B ;

SUSCHITZKY, H .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1976, (02) :141-143

[5] THE SYNTHESIS OF ISOTHIOCYANATES FROM AMINES [J].

HODGKINS, JE ;

ETTLINGER, MG .

JOURNAL OF ORGANIC CHEMISTRY, 1956, 21 (04) :404-405

[6] MODIFIED KALUZA SYNTHESIS .3. SYNTHESIS OF SOME AROMATIC ISOTHIOCYANATES [J].

HODGKINS, JE ;

REEVES, WP .

JOURNAL OF ORGANIC CHEMISTRY, 1964, 29 (10) :3098-&

[7]

ITOH K, 1967, TETRAHEDRON LETT, P2667

[8] CARBODIIMIDES .4. A NOVEL SYNTHESIS OF AROMATIC ISOTHIOCYANATES [J].

JOCHIMS, JC .

CHEMISCHE BERICHTE-RECUEIL, 1968, 101 (05) :1746-&

[9]

Krief A, 1988, ORGANOSELENIUM CHEM, V1

[10]

Liotta D., 1987, ORGANOSELENIUM CHEM

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