CLEAVAGE OF VALIDOXYLAMINE A DERIVATIVES WITH N-BROMOSUCCINIMIDE - PREPARATION OF BLOCKED SYNTHONS USEFUL FOR THE CONSTRUCTION OF CARBA-OLIGOSACCHARIDES COMPOSED OF IMINO LINKAGES

被引：23

作者：

OGAWA, S

NAKAJIMA, A

MIYAMOTO, Y

机构：

[1] Department of Applied Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi, Yokohama

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 12期

关键词：

D O I：

10.1039/p19910003287

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of validoxylamine A and several of its derivatives with N-bromosuccinimide proceeded through cleavage of the imino bonds to give rise to the synthetically useful blocked derivatives of valienamine and validamine, and the cyclohexanone and cyclohexenone derivatives. Some carbatrehalose derivatives were readily prepared by coupling of a pair of these compounds by reductive alkylation with sodium cyanoborohydride.

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页码：3287 / 3290

页数：4

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