SYNTHETIC, STRUCTURAL AND ELECTROCHEMICAL INVESTIGATIONS INTO THE COMPOUND [RU2(MU-O2CCH3)(MU-HNC5H3NCH3)3CL]

被引：31

作者：

MCCARTHY, HJ ^{[1
]}

TOCHER, DA ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,DEPT CHEM,20 GORDON ST,LONDON WC1H 0AJ,ENGLAND

来源：

POLYHEDRON | 1992年 / 11卷 / 01期

关键词：

D O I：

10.1016/S0277-5387(00)83252-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Ru2(O2CCH3)4Cl]n with an excess of H2NC5H3NCH3 in the absence of a solvent gives a near quantitative yield of [Ru2(mu-O2CCH3)(mu-HNC5H3 NCH3)3Cl], which has been characterized by single crystal X-ray diffraction. Electrochemical studies in dimethyl sulphoxide and acetonitrile establish that there are a series of related compounds containing the [Ru2]n+ (n = 3, 4, 5, 6) core.

引用

页码：13 / 20

页数：8

共 20 条

[1] ELECTROCHEMICAL STUDIES ON 3 POLAR DIRUTHENIUM(II,III) COMPLEXES [J].

CHAKRAVARTY, AR ;

COTTON, FA ;

TOCHER, DA ;

TOCHER, JH .

POLYHEDRON, 1985, 4 (08) :1475-1478

[2] SYNTHESIS AND MOLECULAR-STRUCTURE OF THE POLAR, BINUCLEAR COMPLEX, MONOCHLOROTETRA-(6-FLUORO-2-OXOPYRIDINE)DIRUTHENIUM(II,III) [J].

CHAKRAVARTY, AR ;

COTTON, FA ;

SCHWOTZER, W .

POLYHEDRON, 1986, 5 (11) :1821-1827

[3] A NEW MIXED-LIGAND DIRUTHENIUM(II) COMPOUND - SYNTHESIS AND CHARACTERIZATION OF "[RU2CL(ME2PCH2PME2)2(PHNPY)2][BPH4] [J].

CHAKRAVARTY, AR ;

COTTON, FA ;

FALVELLO, LR .

INORGANIC CHEMISTRY, 1986, 25 (02) :214-219

[4] SYNTHESIS AND MOLECULAR-STRUCTURE OF RU2(C5NH4NH)6(PME2PH)2, A RU RU-BONDED MOLECULE WITH 2-PYRIDINYLAMIDE LIGANDS IN 3 COORDINATION MODES AND OTHER NOVEL FEATURES [J].

CHAKRAVARTY, AR ;

COTTON, FA ;

TOCHER, DA .

INORGANIC CHEMISTRY, 1984, 23 (24) :4030-4033

[5] SYNTHESIS, STRUCTURE, AND PROPERTIES OF CHLOROBIS(ACETATO)BIS(6-METHYL-2-HYDROXYPYRIDINATO)DIRUTHENIUM(II,III), THE 1ST RU2(5+) COMPOUND WITH A MIXED SET OF BRIDGING LIGANDS [J].

CHAKRAVARTY, AR ;

COTTON, FA ;

TOCHER, DA .

INORGANIC CHEMISTRY, 1985, 24 (18) :2857-2861

[6] DISPLACIVE TRANSFER OF A PHENYL GROUP FROM TRIPHENYLPHOSPHINE TO A METAL ATOM - SYNTHESIS AND MOLECULAR-STRUCTURE OF RU2PH2(PHCONH)2[PH2POC(PH)N]2 [J].

CHAKRAVARTY, AR ;

COTTON, FA ;

TOCHER, DA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (21) :6409-6413

[7] MIXED-LIGAND COMPLEXES OF DIRUTHENIUM(II, III) - SYNTHESES AND MOLECULAR-STRUCTURES OF CHLORO-BIS-(ACETATO)-BIS-(2-ANILINOPYRIDINATO)(2-ANILINOPYRIDINE)-DIRUTHENIUM.METHYLENE CHLORIDE AND CHLORO-(ACETATO)-TRIS(6-CHLORO-2-OXYPYRIDINATO)DIRUTHENIUM.METHYLENE CHLORIDE [J].

CHAKRAVARTY, AR ;

COTTON, FA .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 105 (01) :19-29

[8] A NEW DIRUTHENIUM(II,III) COMPOUND, RU2(C=CPH)(PHNPY)4.2CH2CL2, WITH AN AXIAL ETA-1-ACETYLIDE LIGAND [J].

CHAKRAVARTY, AR ;

COTTON, FA .

INORGANICA CHIMICA ACTA, 1986, 113 (01) :19-26

[9] SYNTHESES, MOLECULAR-STRUCTURES, AND PROPERTIES OF 2 POLAR DIRUTHENIUM(II,III) COMPLEXES OF 2-HYDROXYPYRIDINE AND 2-ANILINOPYRIDINE [J].

CHAKRAVARTY, AR ;

COTTON, FA ;

TOCHER, DA .

INORGANIC CHEMISTRY, 1985, 24 (02) :172-177

[10] NEW ISOMERIC FORM OF THE M2(OC5H3NCL)4 CORE - A POLAR ARRANGEMENT OF THE 4 6-CHLORO-2-HYDROXYPYRIDINATO (CHP) LIGANDS IN A CHLORODIRUTHENIUM(II,III) COMPLEX, RU2CL(CHP)4 [J].

CHAKRAVARTY, AR ;

COTTON, FA ;

TOCHER, DA .

INORGANIC CHEMISTRY, 1985, 24 (08) :1263-1267

← 1 2 →