MESOMORPHIC TRANSITION-METAL COMPLEXES .4. DITHIENE COMPLEXES OF NI, PD, AND PT

被引：68

作者：

MUELLERWESTERHOFF, UT

NAZZAL, A

COX, RJ

GIROUD, AM

机构：

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1980年 / 56卷 / 08期

关键词：

D O I：

10.1080/01406568008070500

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rational synthesis of transition metal dithiene complexes with mesophorphic properties is reported. In addition to the nickel complexes described earlier the Pd and Pt congerers were also obtained. While the Ni and Pt complexes show, depending on the length of the para-n-alkyl chains, smectic or nematic mesophases, the Pd complexes have no mesomorphic properties at all. It is suggested that the reason for the absence of a mesophase in the Pd complexes is caused by the formation of dimers.

引用

页码：249 / 255

页数：7