PREPARATION OF NOVEL SIGMA-BONDED ORGANOZIRCONIUM(IV) PORPHYRINS AND PHOTOREDUCTION TO THE ZIRCONIUM(II) COMPLEX BY VISIBLE-LIGHT

被引：28

作者：

SHIBATA, K ^{[1
]}

AIDA, T ^{[1
]}

INOUE, S ^{[1
]}

机构：

[1] UNIV TOKYO, FAC ENGN, DEPT SYNTHET CHEM, BUNKYO KU, TOKYO 113, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 07期

关键词：

D O I：

10.1246/cl.1992.1173

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of (5, 10, 15, 20-tetraphenylporphinato)zirconium diacetate ((TPP)Zr(OAc)2) with organo-lithium or -magnesium compounds gave the corresponding sigma-bonded organozirconium(IV) porphyrins ((TPP)ZrR2, R = Me, Et, n-Bu, and Ph). Irradiation of (TPP)ZrMe2 with visible light resulted in a clean generation of the low-valent zirconium(H) porphyrin complex.

引用

页码：1173 / 1176

页数：4

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