EXACT FORMULA FOR THE CONTACT VALUE OF THE DENSITY PROFILE OF A SYSTEM OF CHARGED HARD-SPHERES NEAR A CHARGED WALL

被引：264

作者：

HENDERSON, D

BLUM, L

LEBOWITZ, JL

机构：

[1] UNIV PUERTO RICO,DEPT PHYS,RIO PIEDRAS,PR 00931

[2] RUTGERS STATE UNIV,HILL CTR,DEPT MATH,NEW BRUNSWICK,NJ 08903

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1979年 / 102卷 / 03期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0022-0728(79)80459-3

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

An exact formula for the contact value of the density of a system of charged hard spheres near a charged hard wall is obtained by means of a general statistical mechanical argument. In addition, a formula for the contact value of the charge profile in the limit of large field is obtained. Comparison with the corresponding expressions in the Poisson-Boltzmann theory of Gouy and Chapman shows that these latter expressions become exact for large fields, independent of the density of the hard spheres. © 1979 Elsevier Sequoia S.A.

引用

页码：315 / 319

页数：5

共 4 条

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[2]

Gouy M., 1910, J PHYS THEOR APPL, V9, P457, DOI DOI 10.1051/JPHYSTAP:019100090045700

[3] SOME EXACT RESULTS AND APPLICATION OF MEAN SPHERICAL APPROXIMATION TO CHARGED HARD SPHERES NEAR A CHARGED HARD WALL [J].

HENDERSON, D ;

BLUM, L .

JOURNAL OF CHEMICAL PHYSICS, 1978, 69 (12) :5441-5449

[4] APPLICATION OF THE HYPERNETTED CHAIN APPROXIMATION TO THE ELECTRIC DOUBLE-LAYER AT A CHARGED PLANAR INTERFACE [J].

HENDERSON, D ;

BLUM, L ;

SMITH, WR .

CHEMICAL PHYSICS LETTERS, 1979, 63 (02) :381-383

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