THE C2-DELTA-R-A2-PI-I TRANSITION OF THE (CO+)-C-12 AND (CO+)-C-13 IONS - NEW ROTATIONAL ANALYSIS AND ISOTOPE EFFECT STUDIES

被引：17

作者：

COSSART, D

COSSARTMAGOS, C

机构：

[1] Laboratoire de Photophysique Moléculaire, CNRS, Université Paris-Sud, 91405 Orsay Cédex

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1990年 / 141卷 / 01期

关键词：

D O I：

10.1016/0022-2852(90)90278-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Use of a special emission source allowed recording of high-resolution spectra for the C2Δ-A2Π transition of the CO+ ion. Relative to previous work, the new information on the C2Δ state was as follows: 1. (i) determination of the vibrational numbering from the isotopic spectra, 2. (ii) substantial corrections in the spin-orbit and rotational constants, 3. (iii) evidence for an electron configuration change with increasing vibrational quantum number. © 1990.

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页码：59 / 78

页数：20

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