REAL-TIME MEASUREMENTS OF THE GAS-PHASE ADSORPTION OF NORMAL-ALKYLTHIOL MONOLAYERS AND MULTILAYERS ON GOLD

被引：152

作者：

THOMAS, RC

SUN, L

CROOKS, RM

RICCO, AJ

机构：

[1] UNIV NEW MEXICO,DEPT CHEM,ALBUQUERQUE,NM 87131

[2] UNIV NEW MEXICO,CTR HIGH TECHNOL MAT,ALBUQUERQUE,NM 87131

[3] SANDIA NATL LABS,DIV MICROSENSOR 1163,ALBUQUERQUE,NM 87185

来源：

LANGMUIR | 1991年 / 7卷 / 04期

关键词：

D O I：

10.1021/la00052a004

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Results of surface acoustic wave, ellipsometric, and electrochemical experiments indicating that stable mono- or multilayer films result from the gas-phase chemisorption of n-alkylthiol molecules onto Au substrates are reported. Measurement of the mass and thickness of CH3(CH2)6SH films indicates a single, stable monolayer, while CH3(CH2)15SH deposition results in mono- or multilayers depending upon the experimental conditions. The first in situ kinetic measurements of the self-assembly of such layers are also discussed.

引用

页码：620 / 622

页数：3

共 31 条

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