CATALYSIS OF DIELS-ALDER REACTIONS BY METALLOPORPHYRINS

被引：18

作者：

BARTLEY, DW ^{[1
]}

KODADEK, TJ ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM & BIOCHEM,AUSTIN,TX 78712

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 44期

关键词：

D O I：

10.1016/S0040-4039(00)97048-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aluminium (111) tetraphenyl porphyrin chloride (AITPPCl) has been shown to catalyze Diels-Alder reactions of α,β-unsaturated carbonyl compounds in moderate yield. Selectivity based on electronic effects is exhibited which is different from that seen with catalysts such as diethylaluminlum chloride. © 1990.

引用

页码：6303 / 6306

页数：4

共 11 条

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