A NEW C-60 POLYMER VIA RING-OPENING METATHESIS POLYMERIZATION

被引：61

作者：

ZHANG, NJ

SCHRICKER, SR

WUDL, F

PRATO, M

MAGGINI, M

SCORRANO, G

机构：

[1] UNIV CALIF SANTA BARBARA,INST POLYMERS & ORGAN SOLIDS,SANTA BARBARA,CA 93106

[2] CNR,CTR MECCANISMI REAZ ORGAN,DIPARTIMENTO CHIM ORGAN,I-35131 PADUA,ITALY

来源：

CHEMISTRY OF MATERIALS | 1995年 / 7卷 / 03期

关键词：

D O I：

10.1021/cm00051a001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The quadricyclane adduct of C-60 1 contains a norbornene moiety that can be used in the copolymerization with norbornene. The ROMP copolymerization of the two monomers (1% of 1) affords a material that is thermally stable, while retaining the unique electronic and electrochemical properties of the fullerene C-60. The polymer 2 is soluble in the organic solvents and free-standing films can be easily obtained by evaporation of chloroform solutions on a glass substrate.

引用

页码：441 / 442

页数：2

共 7 条

[1] LIVING RING-OPENING METATHESIS POLYMERIZATION OF 2,3-DIFUNCTIONALIZED 7-OXANORBORNENES AND 7-OXANORBORNADIENES BY MO(CHCME2R)(N-2,6-C6H3-ISO-PR2)(O-TERT-BU)2 AND MO(CHCME2R)(N-2,6-C6H3-ISO-PR2)(OCME2CF3)2 [J].