VERSATILE THIN-LAYER SPECTROELECTROCHEMICAL CELL EMPLOYING SPECULAR REFLECTANCE

被引：17

作者：

HINMAN, AS

PAVELICH, BJ

机构：

[1] Department of Chemistry, University of Calgary, Calgary,AB,T2N IN4, Canada

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1987年 / 65卷 / 05期

关键词：

Transparent electrodes - Inorganic compounds - Cyclic voltammetry - Spectroelectrochemistry;

D O I：

10.1139/v87-155

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A versatile thin layer spectroelectrochemical cell employing specular reflection of the incident light beam from the electrode surface is described. Its application to in-situ uv-vis and FTIR characterization of the products of electrochemical reactions and to thin layer voltammetry and coulometry as well as conventional cyclic voltammetry is demonstrated for the oxidation of tetraphenylporphinatozinc in dichloroethane/tetrabutylammonium perchlorate solution. The advantages and disadvantages of this type of cell as compared to more conventional sandwich type optically transparent thin layer electrodes are discussed.

引用

页码：919 / 923

页数：5

共 22 条

[1]

DEANGELIS TP, 1976, J CHEM ED, V53, P529

[2]

DOLPHIN D, 1979, PORPHYRIN CHEM ADV, P335

[3] INSITU INFRARED SPECTROELECTROCHEMISTRY [J].