ANALYSIS OF FLUORESCENCE SPECTRA OF EUROPIUM(3)-BIS-PHENANTHROLINE-TRIS-CARBOXYLATE COMPLEXES

被引：44

作者：

SINHA, SP

BUTTER, E

机构：

[1] Department of Inorganic Chemistry, The University

[2] Institut für Anorganische Chemie Karl-Marx-Universität, Leipzig

来源：

MOLECULAR PHYSICS | 1969年 / 16卷 / 03期

关键词：

D O I：

10.1080/00268976900100331

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The fluorescence spectra of microcrystalline complexes of the composition Eu(phen)2(benz)3, Eu(phen)2(sal)3, and Eu(phen)2(p-OH-benz)3 have been investigated under high resolution at room temperature and 77°k. The effective Eu(III) site symmetries for Eu(phen)2(benz)3(C2v) and Eu(phen)2(sal)3(D2) complexes have been established with the help of group theoretical reasoning. The Eu(III) fluorescence lines for Eu(phen)2(p-OH-benz)3 complex are very broad and weak even at 77°k; reasons for this weakness are given. A comparison of fluorescence intensities of Eu(phen)2(benz)3 and Eu(phen)2(sal)3 with other bis-phenanthroline complexes has been presented. © 1969 Taylor and Francis Group, LLC.

引用

页码：285 / &

共 29 条

[1] RADIATIVE TRANSITION PROBABILITIES WITHIN 4FN CONFIGURATIONS - FLUORESCENCE SPECTRUM OF EUROPIUM ETHYLSULFATE [J].